IIR Rubber

Product Overview

 

IIR Rubber (Butyl Rubber) is a synthetic elastomer synthesized via the copolymerization of isobutylene with a small amount of isoprene. Its primary industrial value lies in its exceptional impermeability to gases and moisture, combined with outstanding resistance to heat, aging, ozone, and polar chemicals.


Engineered for critical sealing, dampening, and containment tasks, IIR rubber maintains stable physical properties across wide temperature swings. It is utilized in continuous production runs or customized configurations (rolls, sheets, gaskets, and molded technical parts) based on specific mechanical and environmental specifications.

 

 
 
Product Specifications & Technical Data Sheet (TDS)

 

Standard industrial custom IIR rubber molded parts and extruded components adhere to ASTM D2000 classification standards. Custom formulations are available upon request to meet specialized regulatory or mechanical targets.

Property

Standard Value / Range

Test Method

Polymer Base

Isobutylene Isoprene Rubber (IIR) / CIIR / BIIR

FTIR / DSC

Hardness Range

40 to 80 Shore A (± 5)

ASTM D2240

Tensile Strength

7 to 18 MPa (Depending on filler loading)

ASTM D412

Elongation at Break

300% to 600%

ASTM D412

Compression Set

<= 25% (22 h at 70°C)

ASTM D395 Method B

Temperature Range

-40°C to +120°C (Continuous)

ASTM D573

Gas Permeability

Extremely low (1/10th of natural rubber)

ASTM D1434

Standard Thickness

1.0 mm to 50.0 mm (Sheets); Custom (Molded)

ISO 3302-1 Class M1

 

Material & Compound

The performance profile of IIR rubber is dictated by polymer architecture and compounding ingredients. The backbone features a saturated hydrocarbon chain with minimal unsaturation sites, limiting cross-linking density and restricting molecular mobility—the physical mechanism responsible for its low gas permeability and high butyl rubber gas permeability spec performance.

 
 

Polymer Grades:

Utilization of general-purpose IIR, Chlorobutyl (CIIR), and Bromobutyl (BIIR) polymers. Halogenated grades offer superior adhesion to metals and faster curing rates when co-vulcanization with other rubbers is required.

 
 
 

Reinforcing Fillers:

High-structure carbon blacks (e.g., N550, N770) or mineral fillers (calcined clays) are incorporated to optimize tensile strength and tear resistance without degrading elasticity.

 
 
 

Curing Systems:

Resin-cured systems are standard for heat-resistant applications, while sulfur-cured systems are applied for general industrial sealing. Curing kinetics are monitored via moving die rheometer (MDR) testing prior to batch release.

 

 

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Product Construction / Design

Form Factors:
• Calendered Sheets & Rolls: Uniform thickness with smooth or fabric-impression finishes. Available with or without pressure-sensitive adhesive (PSA) backings.
• Extruded Profiles: Solid cords, hollow tubes, and custom channel sections produced via continuous extrusion and hot-air or salt-bath vulcanization lines.
• Molded Components: Compression, transfer, and injection-molded parts manufactured to tight geometrical tolerances.


Dimensional Tolerances: Molded items conform to ISO 3302-1 (Class M1 for precision parts). Extruded profiles adhere to DIN ISO 3302-1 E2 standards.

 

Performance Characteristics

 

Gas & Moisture Barrier:

Demonstrates the lowest gas and vapor transmission rates among general-purpose elastomers, preventing pressure loss in pneumatic and vacuum systems.

01

Chemical Resistance:

Excellent resistance to inorganic acids, alkalis, polar solvents, brake fluids (glycol-based), and animal/vegetable oils. Incompatible with petroleum-based oils, gasoline, and aromatic solvents.

02

Weathering & Ozone:

High resistance to oxygen, ozone, UV radiation, and sunlight degradation without developing surface cracking.

03

Dynamic Damping:

Exhibits high mechanical loss factor (tan delta) across a broad frequency spectrum, making it effective for shock absorption and vibration isolation.

04

Electrical Properties:

High dielectric strength and volume resistivity, suitable for high-voltage insulation applications.

05

 

Available Options

Hardness:

Custom formulations adjustable from 40 to 80 Shore A.

 

Color:

Standard black, grey, white (FDA-compliant formulations available), and custom pigment matching.

Reinforcement Inserts:

Integration of polyester, nylon, or fiberglass fabric plies within elastomer sheets to improve tensile modulus and bolt-load retention in flanged joints.

Surface Treatments:

Chlorination or silicone-free mold-release treatments available to reduce surface friction or prepare parts for secondary bonding.

 

Manufacturing Process

 

Production follows strict batch tracking and process control protocols to ensure physical property uniformity.
• Compound Mixing: Raw IIR polymers, fillers, plasticizers, and curing agents are dispersed in an internal intermeshing mixer (Banbury mixer) under controlled thermal parameters to prevent premature scorching.
• Milling & Straining: Mixed compounds pass through a two-roll mill and a strainer-extruderd to remove particulate contaminants and homogenize the compound sheet.


Forming:
Sheets are produced via 4-roll calenders with automated thickness gauge control.
Molded parts are shaped using multi-cavity hydraulic presses equipped with programmable logic controllers (PLCs) regulating temperature, tonnage, and dwell time.
• Vulcanization (Curing): Cross-linking occurs under heat and pressure, fixing the permanent elastic structure.
• Deflashing & Post-Curing: Automated cryogenic deflashing or precision trimming removes flash from molded parts. Post-curing ovens stabilize volatile organic compounds and complete cross-linking reactions.

 

Applications

Fluid & Gas Containment:

Inner liners for pneumatic accumulators, diaphragms for pressure regulators, and vacuum chamber seals.

Automotive & Transportation:

Tire innerliners, radiator hoses, body mounts, and suspension damping buffers.

Electrical Infrastructure:

Cable joint insulation, transformer seals, and high-voltage substation gaskets.

Pharmaceutical & Medical:

Stopper vials, syringe plungers, and fluid transfer tubing requiring low extractables and minimal gas transmission.

 

Industries Served

 

 

  • Industrial Fluid Power & Pneumatics
  • Automotive Tier-1 Manufacturing
  • Electrical Power Transmission
  • Pharmaceutical & Chemical Processing
  • Heavy Equipment & Agricultural Machinery

 

 

Standards & Quality Control

Internal quality management systems operate under ISO 9001 standards. Verification is performed at each stage of production.


Raw Material Testing: Mooney viscosity (ASTM D1646) and specific gravity verification on incoming polymer lots.


Rheological Testing: Cure characteristics (scorch time, cure rate index) measured via oscillating disc rheometer for every mixed batch.


Physical Testing: In-house laboratory assessment of tensile strength, elongation, hardness, and compression set on cured test slabs from production lots.


Dimensional Inspection: Optical comparators and digital coordinate measuring machines (CMM) applied to custom molded tooling samples.


Regulatory Compliance: Compounds can be formulated to meet FDA 21 CFR 177.2600 (food contact), USP Class VI, RoHS, and REACH directives.

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OEM / Custom Manufacturing
 

Engineering support accommodates custom part development from concept to full-scale production as a reliable chlorobutyl rubber sheet supplier and custom compounder.

Tooling Development:

In-house CAD/CAM tool design and CNC machining of steel or aluminum molds for rapid prototyping and production tooling.

Compound Customization:

Formulation adjustments tailored to specific chemical resistance, temperature limits, or regulatory mandates.

Prototyping Services:

Sample runs and 3D-printed master models for fit and function testing prior to production tooling investment.

 

Packaging & Delivery

 

Rolls & Sheets: Wound on rigid cardboard cores, wrapped in moisture-barrier polyethylene film, and secured on fumigated wooden pallets or in heavy-duty export cartons.


Molded Parts: Packed in anti-static, sealed poly bags within reinforced corrugated master cartons to prevent transit deformation and contamination.


Logistics: Direct sea and air freight capabilities with custom-tailored labeling, barcode tagging, and Certificate of Analysis (CoA) inclusion with every shipment.

 

 

FAQ

 

 

Q: What is the primary advantage of IIR rubber over EPDM or NBR?

A: IIR rubber offers superior gas and moisture impermeability compared to EPDM and NBR, making it the preferred elastomer for vacuum seals and pneumatic applications where pressure retention is critical. However, unlike NBR, it is not resistant to petroleum-based oils.

Q: Can IIR rubber compounds be formulated for food-contact applications?

A: Yes. Specific formulations utilize FDA-compliant ingredients meeting 21 CFR 177.2600 standards for repeated use in food and beverage processing equipment.

Q: What is the maximum continuous service temperature for standard IIR grades?

A: Standard industrial IIR compounds withstand continuous operating temperatures up to +120°C (248°F). Special heat-resistant formulations can endure up to +130°C to +140°C for limited durations.

Q: How do you ensure batch-to-batch physical property consistency?

A: Every mixed compound batch undergoes rheometer testing to verify cure profiles, alongside tensile, hardness, and elongation tests on vulcanized test pieces before parts are released to production or shipment.

Q: What information is required to request a custom molded IIR component?

A: RFQs should include a 2D drawing or 3D CAD model, required hardness (Shore A), operating temperature range, media contact environment, estimated annual usage (EAU), and any required regulatory compliances (such as FDA or REACH).

Q: What is the standard lead time for custom molded parts versus standard sheet stock?

A: Standard calendered sheets and rolls in standard thicknesses are typically stocked for immediate dispatch. Custom molded parts require 3 to 4 weeks for prototype tooling and initial sample submission (PPAP), with production lead times following sample approval.

 

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